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New Synthetic Method of Perfluoro-Silanes for the Stable Electrolyte of Lithium Ion Battery Application

초록

영어

Non-hydrolyzable fluorinated organosilicon compounds as an eletrolyte for the application of lithium-ion batteries (LIB) are synthesized. New synthetic method for the perfluorinated organosilicon compound containing spacer such as ethyl and propyl group with cyano moiety instead of ethylene glycol to prevent hydrolysis and to promote conductivity are developed in one pot reaction with moderately high yield. Air-sensitive boron trifluoride etherate is no longer required in this reaction. The products are characterized by spectroscopic analysis.

목차

Abstract
 1. Introduction
 2. Experimental Section
  2.1. Synthesis of 4-(Trifluorosilyl)butanenitrile
  2.2. Synthesis of 3-(Trifluorosilyl)propanenitrile
 3. Results and Discussion
 4. Conclusions
 Acknowledgments
 References

저자정보

  • Kyungkuk Koh Department of Chemistry, Chosun University, Gwangju 501-759, Korea
  • Honglae Sohn Department of Chemistry, Chosun University, Gwangju 501-759, Korea

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