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purpose : The purpose of this study was to evaluate the effect of the chemical surface treatment on the flexural bond strength of heat curing denture base resin and reliners. Methods: Denture base resin surface was treated with MMA 95% and TEGDMA 5%, MMA 95% and silane coupling agent 5%, heat curing resin monomer. After denture reliners were injected, flexural bond strength was measured. Results: The repair resin of Vertex SC was higher than Lang, hard reliner of Kooliner was higher than Rebase. Soft reliner of Dura base and Coe-soft showed differently according to the surface treatment. The all chemical treatment groups on Vertex SC were significantly higher than control(p<0.05). In Lang group, 5% MPS treated group showed significantly higher flexural bond strength than others(p<0.05). In Kooliner group, all chemical treatment groups showed significantly higher than control(p<0.05). In Rebase group, the 5% MPS and the monomer denture base resin treated groups showed significantly higher than others(p<0.05). In Dura base group, 5% MPS treated group showed significantly higher flexural bond strength than others(p<0.05). In Coe-soft group, all treated groups were significantly higher than control group(p<0.05). Conclusion: TEGDMA, MPS, and the monomer of heat-cured denture base resin were effective to improve the bond strengths between denture base and denture relining materials. Especially, 5% MPS expected to strengthen effectively the bonding property of denture base and denture reliners within the results of this study.