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논문검색

Investigation of Coke Formation in Dry Methane Reforming over Nickel-based Monolithic Catalysts

초록

영어

Coking accumulations via dry methane reforming (DMR) over 10NAM monolithic catalyst and pelletized catalyst was investigated. 10NAM catalyst was synthesized and coated on a wall of monolithic reactor. Pelletized catalyst of 10NAM was also prepared for the comparison. Consequently, catalyst was characterized by BET, H2-TPR and H2-TPD. The catalytic reaction was undergone at 600oC under atmospheric pressure and CH4 to CO2 reactant ratio of 1:2. The coking formation over spent catalyst was then carried out in the hydrogen flow using temperature programmed technique (TPH). According to the results, DMR over 10NAM monolithic catalyst exhibits a minimized coking formation comparing to the use of pelletized catalyst. This could be attributed to a prominent heat transfer efficiency of the monolithic catalyst.

목차

Abstract
 1. Introduction
 2. Experimental
  2.1 Catalyst preparation
  2.2 Catalyst characterizatio
  2.3 Catalytic reaction test
 3. Results and discussion
  3.1 Catalyst characterization
  3.2 Performance of dye methane reforming reaction
 4. Conclusions
 Acknowledgements
 References

저자정보

  • Pongsakorn Pornruangsakun Department of Industrial Chemistry, King Mongkut’s University of Technology North Bangkok, Bangkok, Thailand, Research and Development Center for Chemical Engineering Unit Operation and Catalyst Design (RCC), King Mongkut’s University of Technology North Bangkok, Bangkok , Thailand
  • Sabaithip Tungkamani Department of Industrial Chemistry, King Mongkut’s University of Technology North Bangkok, Bangkok, Thailand, Research and Development Center for Chemical Engineering Unit Operation and Catalyst Design (RCC), King Mongkut’s University of Technology North Bangkok, Bangkok , Thailand
  • Tanakorn Ratana Department of Industrial Chemistry, King Mongkut’s University of Technology North Bangkok, Bangkok, Thailand, Research and Development Center for Chemical Engineering Unit Operation and Catalyst Design (RCC), King Mongkut’s University of Technology North Bangkok, Bangkok , Thailand
  • Monrudee Phongaksorn Department of Industrial Chemistry, King Mongkut’s University of Technology North Bangkok, Bangkok, Thailand, Research and Development Center for Chemical Engineering Unit Operation and Catalyst Design (RCC), King Mongkut’s University of Technology North Bangkok, Bangkok , Thailand
  • Thana Sornchamni PTT Public Company Limited, Bangkok, Thailand

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