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The effect of CO2 Reduction by electron reaction in Rhodobacter sphaeroides Immobilized on the Photosensitizers, Zinc Pthalocyanine and Copper Phthalocyanine

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Phthalocyanine derivatives have perhaps received more attention than any other class of dyes as sensitizers for photodynamic therapy and most favoured are the aluminium and zinc derivatives. Photoinduced electron transfer in donor-acceptor molecules has been extensively studied, in particular for covalently linked dyeds in solution as model systems of natural photosynthesis to harvest efficiently solar energy. In this study, the improvements as electron transport from immobilization of R. sphaeroides on two phthalocyanines were evaluated. In order to determine electron reaction of cell bound phthalocyanines, we are confirmed cyclic voltammetry measurement. R. sphaeroides bound ZnPc in water solvent and CuPc in SDS solvent were shown active electron reactions. It was correlated with the amount of cell bound phthalocyanines. In addition, cell bound phthalocyanine was effected on CO2 reduction under light dark condition cultured R. sphaeroides. Phthalocyanines as electron donoron R. sphaeroides can apply for improving photosynthetic efficiency.

저자정보

  • Hyun Jeong LEE Graduate School of Semiconductor and Chemical Engineering, Chonbuk National University, Jeonju, 561-756.
  • Yang-Hoon KIM Department of Microbiology, Chungbuk National University, 410 Sungbong-Ro, Heungduk-Gu, Cheongju, 361-763.
  • Jiho MIN Graduate School of Semiconductor and Chemical Engineering, Chonbuk National University, Jeonju, 561-756.

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