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Poster-24

Synthesis of the hexasaccharide repeating unit of the cell wall polymer from Kineosoriaaurantiaca

초록

영어

Properly protected hexasaccharide was synthesized by employing the glycosyl phthalate method from a trisaccharide acceptor and a trisaccharide donor, both of which were obtained by deprotection of a common trisaccharide precursor. Trisaccharide was prepared by assembly of three monosaccharide building blocks through two β-mannosyl linkages. The mannosyl phthalate donor for the disaccharide synthesis and the CB glycoside donor for the trisaccharide synthesis were achieved in the 4, 6-O-benzylidene directed β -mannosylation.

저자정보

  • Mi Hyun Kim Center for Bioactive Molecular Hybrids and Department of Chemistry, Yonsei University, Seoul
  • Kwan Soo Kim Center for Bioactive Molecular Hybrids and Department of Chemistry, Yonsei University, Seoul

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