원문정보
초록
영어
Polymerization of vinyl monomers is promoted by thianthrene cation radical as a part of our research concerning the reactions of various agents with readily isolable, yet highly reactive species and elucidate the biological activity. Thianthrene cation radical initiated the homopolymerization and copolymerization of styrene and ethyl vinyl ether. The polymerization yields decreased as the concentration of phenylacetylene or diphenylethylene increased. Such polymereization by cationic thianthrene radical could provide some clues for the reaction in living animals. Comments on possible polymerization mechanisms were suggested.
목차
1. Introduction
2. Experimental
2.1. Materials
2.2. Instrumentation
2.3. Polymerization of styrene with thianthrene cation radical perchlorate
2.4. Polymerization of ethyl vinyl ether with thianthrene cation radical perchlorate
2.5. Copolymerization of styrene and ethyl vinyl ether with thianthrene cation radical perchlorate
3. Results and Discussion
4. Conclusions
Acknowledgements
References