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Polymerization of Vinyl Monomers Initiated by Thianthrene Cation Radical with Potential Biological Activity

원문정보

초록

영어

Polymerization of vinyl monomers is promoted by thianthrene cation radical as a part of our research concerning the reactions of various agents with readily isolable, yet highly reactive species and elucidate the biological activity. Thianthrene cation radical initiated the homopolymerization and copolymerization of styrene and ethyl vinyl ether. The polymerization yields decreased as the concentration of phenylacetylene or diphenylethylene increased. Such polymereization by cationic thianthrene radical could provide some clues for the reaction in living animals. Comments on possible polymerization mechanisms were suggested.

목차

Abstract
 1. Introduction
 2. Experimental
  2.1. Materials
  2.2. Instrumentation
  2.3. Polymerization of styrene with thianthrene cation radical perchlorate
  2.4. Polymerization of ethyl vinyl ether with thianthrene cation radical perchlorate
  2.5. Copolymerization of styrene and ethyl vinyl ether with thianthrene cation radical perchlorate
 3. Results and Discussion
 4. Conclusions
 Acknowledgements
 References

저자정보

  • Beomgi Lee Department of Biotechnology, Chosun University, Gwangju 501-759, Korea
  • Seongsim Kim Department of Biotechnology, Chosun University, Gwangju 501-759, Korea
  • Jaeyoung Park Department of Biotechnology, Chosun University, Gwangju 501-759, Korea
  • Hyeonsook Cheong Department of Biotechnology, Chosun University, Gwangju 501-759, Korea
  • Ji Eun Noh Department of Chemistry and Nanotechnology Research Center, Chonnam National University, Gwangju 500-757, Korea
  • Hee-Gweon Woo Department of Chemistry and Nanotechnology Research Center, Chonnam National University, Gwangju 500-757, Korea

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