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초록
영어
A newly-devised Meerwein-Ponndorf-Verley (MPV) reagents, such as diisobutylacetoxyalanes and diisobutylmethanesulfonylalanes, achieved a clean conversion of unsymmetrical epoxides to the corresponding less substituted alcohols. This review covers the recent developments for such a regiospecific ring-opening reaction of epoxides.
목차
Abstract
1. Introduction
2. Mechanistic Consideration of the MPV Reactions
2.1. Aluminum Reagents
2.2. Boron Reagents
2.3. Appearance of New MPV Type Reagents
2.4. Auminum – Containing Reagents
2.5. Boron – Containing Reagents
2.6. Application for Organic Synthesis
2.7. General Reducing Characteristics of Diisobutylaluminum and Diisopinocampheylboron Derivatives Toward Common Organic Functional Groups
2.8. Regioselective Ring-opening of Epoxide
3. Concluding Remarks
References
1. Introduction
2. Mechanistic Consideration of the MPV Reactions
2.1. Aluminum Reagents
2.2. Boron Reagents
2.3. Appearance of New MPV Type Reagents
2.4. Auminum – Containing Reagents
2.5. Boron – Containing Reagents
2.6. Application for Organic Synthesis
2.7. General Reducing Characteristics of Diisobutylaluminum and Diisopinocampheylboron Derivatives Toward Common Organic Functional Groups
2.8. Regioselective Ring-opening of Epoxide
3. Concluding Remarks
References
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