원문정보
Fabrication of Organic Electrolytes for Electric Double Layer Capacitor with Activated Carbon Cloth Electrode
초록
영어
Electrochemical charateristics of activated carbon fiber cloth(ACFC) electrode were studied with propylene carbonate(PC), r-butyrolactone(GBL) and N,N-dimethyl-formamide(DMF) as a solvent and tetraethylammoniumtetrafluoroborate(TEABF4), tetraethylammoniumhexafluorophosphate(TEABF6), tetrabutylammoniumtetrafluoroborate(TBABF4) and tetrabutylammonium hexafluorophosphate(TBAPF6) as an electrolytes(active material). The concentrations of electrolytes were in the range of 0.2~1.2 N, the volume ratios of PC and DMF as a mixed solvent system, were 90:10, 80:20, 70:30, 60:40, 50:50, and 40:60 vol%. Electrochemical characteristics such as electric conductivity, internal resistance, and electric capacitance of fabricated unit cells were measured after the moisture of activated material was removed with molecular sieve. Electrochemical characteristics were better in mixed solvents system than in mono solvent system. The mono solvent system of 1.0 N electrolyte of GBL/TEABF4 with activated carbon cloth electrodes showed better result but the mixed solvent system with PC and DMF/TEABF4(50:50 vol%) and the concentration of 1.0 N electrolyte showed the best characteristics. Internal resistance was 3.47 Ω and specific capacitance was 19.1 F/g respectively.y.
목차
1. 서론
2. 실험 방법
2.1. 실험재료
2.2. 전기화학적 특성 측정
2.3. 기본 단위 cell 제조
3. 결과 및 고찰
3.1. 전극의 표면구조 관찰
3.2. 전해액의 전기전도도 측정
3.3. 기본 단위 Cell 의 내부저항
3.4. 비정전용량
4. 결론
참고문헌