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논문검색

Dehydrogenative Polymerization of Hydrosilanes to Silicon Polymers

초록

영어

Hydrosilanes possessing reactive Si-H bond are used in synthesizing various types of polysilanes by dehydrocoupling under the influence of various organometallic promoters.42 Catalytic Si-Si/Si-O coupling of hydrosilanes with hydrosilanes, alcohols, and lactones to silicon-based polymers are described in this article as selective examples of our recent research developments. These silicon-containing polymers can be used as a precursor to prepare useful functional materials for fabricating electronic devices.


목차

Abstract
 1. Introduction
 2. Result and Discussion
  2.1. Linear-Selective Dehydrocoupling of Hydrosilanes to Polysilanes
  2.2. Homodehydrocoupling and Codehydrocoupling of 1,1-Dihydrotetraphenylsilole and 1,1-Dihydrotetraphenylgermoleto Electroluminescent Polymers
  2.3. Si-O/Si-Si Dehydrocoupling of Hydrosilane with Alcohol to Poly(alkoxysilane)s
  2.4. Ring-Opening/Dehydrocoupling of Hydrosilane and Lactone
 Conclusion
 References

저자정보

  • Myoung-Hee Kim Nanotechnology Research Center and Department of Chemistry, Chonnam National University
  • Jun Lee Nanotechnology Research Center and Department of Chemistry, Chonnam National University
  • Soo-Yong Mo Nanotechnology Research Center and Department of Chemistry, Chonnam National University
  • Jong-Hyun Kim Nanotechnology Research Center and Department of Chemistry, Chonnam National University
  • Hee-Gweon Woo Nanotechnology Research Center and Department of Chemistry, Chonnam National University

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