원문정보
초록
영어
Thiophene-derivatized pentiptycenes were synthesized and characterized by NMR and UV-Vis spectroscopy. Aggregation behavior of thiophene-derivatized pentiptycenes was monitored by the measurement of fluorescence. Fluorescence intensities for the thiophene-derivatized pentiptycenes and thiophene-derivatized pentiptycenes aggregates were compared. There is no shift in the maximum of the emission wavelength. In the range of water fraction between 20% and 40%, the emission intensity of thiophene-derivatized pentiptycene aggregates remains almost identical. Fluorescence efficiency incresaed by about 5 times higher when the thiophene-derivatized pentiptycenes forms the aggregates in solution.
목차
1. Introduction
2. Experimental
2.1. Materials
2.2. Synthesis of Iptycene Ouinones
2.3. Synthesis of Bis(trimethylsilylethynyl) Pentiptycene
2.4. Synthesis of Pentiptyene Diacetylene
2.5. Synthesis of Thiophene-derivatized Pentiptyene
2.6. Instrumentation and Experimental Condition
3. Result and Discussion
4. Conclusion
References