earticle

논문검색

Perchlorocyclopentasilnane에 대한 합성방법의 개발과 그의 광학적 특성 조사

원문정보

Development of Synthetic Route for Perchlorocyclopentasilane and Its Optical Characterization

한정민

피인용수 : 0(자료제공 : 네이버학술정보)

초록

영어

Perchlorosilanes are useful precursors for the synthesis of hydrosilanes for the fabrication of electronic devices such as silicon thin-film transistors and silicon nanoparticles. For this solution process, requirements of precursors applicable to solution process are relatively low volatile and soluble in common organic solvents. In this work, the decaphenylcyclopentasilane has been obtained from the reaction of the lithium wire and dichlorodiphenylsilane. The reaction of decaphenylcyclopentasilane with lewis acid catalyst, HCl/AlCl3, gives the perchlorocyclopentasilane. Decaphenylcyclopentasilane exhibits an unusual optical property. Its optical property was characterized by UV-vis and fluorescence spectroscopy. Absorption wavelength maxima for the decaphenylcyclopentasilane was 272 nm. Decaphenylcyclopentasilane displayed an emission band at 741 nm with excitation wavelength of 272 nm.

목차

Abstract
 1. 서론
 2. 실험
  2.1. 일반
  2.2. Decaphenylcyclosilane의 합성
  2.3. Decachlorocyclosilane의 합성
 3. 결과 및 고찰
 4. 결론
 참고문헌

저자정보

  • 한정민 Joungmin Han. 한국화학연구원

참고문헌

자료제공 : 네이버학술정보

    함께 이용한 논문

      ※ 기관로그인 시 무료 이용이 가능합니다.
      ※ 학술발표대회집, 워크숍 자료집 중 4페이지 이내 논문은 '요약'만 제공되는 경우가 있으니, 구매 전에 간행물명, 페이지 수 확인 부탁 드립니다.

      • 4,000원

      0개의 논문이 장바구니에 담겼습니다.