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Viologen유도체의 합성과 광변색 특성

원문정보

A study on the Synthesis and the Photochromic Property of Viologen Derivatives

서구원

피인용수 : 0(자료제공 : 네이버학술정보)

초록

영어

Photopolymers containing carboxyl groups as water soluble groups and o,m or p-nitro substituted benzalacetophenone(o-BAP . NO2, m-BAP . NO2, p-BAP . NO2) as sensitive groups are synthesized by condensing 4- (vinylbenzyloxy)acetophenoneco-methacrylic acid copolymer with o,m or p-nitro substituted benzaldehyde in alkaline catalyzer. These condensation polymer were effectively crosslinked by the irradiation of UV light. Alkaline aqueous developing solution available commercially for negative type presensitized plate can be applied for development of these photopolymers. Relative sensitivities of the condensation polymers in film stars were measured. It is found that order of sensitivity of the synthesized polymer are o-BAP . NO2〈m-BAP . NO2〈 p-BAP . NO2 The spectral sensitivities of p-BAP . NO2 were observed to be 0.03~0.05 mJ/㎠ at 300~400nm respectively

목차

Abstract
 1. 서론
 2. 실험
 시약
  Viologen 유도체 합성
  수용액에서 광변색 측정
  고체 필름상태에서 광변색측정
 3. 결과 및 고찰
  Viologen유도체 분석
  수용액상태에서의 발색
  PVP매질에서 발색
  PVP매질에서 농도 영향
  PVP매질에서 분자회합
  온도에 따른 스펙트럼 변화
  PVP매질에서의 소색
  광변색의 반복성
 4. 결론
 REFERENCES

저자정보

  • 서구원 Gu Won Suh. 한국조폐공사 연구소

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