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In this study, the sintering mechanism of woodceramics (WCs) from cashew nut shell waste (CNSW) was studied by analyzingchemical reactions and structural changes during the sintering process of of CNSW powder, liquefied wood and green bodiesof WCs at 900 oC for 60 minutes in the CO2 atmosphere. The chemical and structural properties of the products wereinvestigated by X-ray diffraction (XRD), Raman spectroscopy, Fourier Transform Infrared (FTIR), and scanning electronmicroscope (SEM). The results showed that the decomposition reactions of liquefied wood and CNSW occurred simultaneouslyto form the hard carbon and the soft carbon at high temperature. The sintering mechanism of WCs has been presented.